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Synthesis and Crystal Structure of μ‐Thiobis[tris(diethyldithiocarbamato)molybdenum( IV )‐Toluene 1:1, a Compound Containing a Rare MoSMo Core
Author(s) -
Jasim Khalid S.,
Chieh Chung,
Mak Thomas C. W.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198607491
Subject(s) - toluene , molybdenum , chemistry , tris , sulfur , crystal structure , ion , medicinal chemistry , stereochemistry , crystallography , inorganic chemistry , organic chemistry , biochemistry
Molybdenum‐sulfur complexes , which are of interest, for example, as model compounds for the active sites of some enzymes, are known in abundance. Mo‐S‐Mo structural units, on the other hand, have only been found in the anion of K 6 [Mo 2 (μ‐S)(CN) 12 ] and in the neutral title compound 1 , which is formed upon passing a stream of air through a solution of [Mo 2 (S 2 CNEt 2 ) 6 ]] in toluene.