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An Isocyanide Radical as Complex Ligand
Author(s) -
Seitz Friedrich,
Fischer Helmut,
Riede Jürgen,
Schöttle Thomas,
Kaim Wolfgang
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198607441
Subject(s) - isocyanide , chemistry , ligand (biochemistry) , radical , photochemistry , stereochemistry , crystallography , organic chemistry , receptor , biochemistry
The stable, neutral complexes 1 and 2, containing the dimesitylmethyl(isocyano) radical , are formed via a SET (single electron transfer) mechanism from the corresponding 2‐azaallenylidene complexes. The structure of 1 (violet crystals) was established by X‐ray structure analysis (R = mesityl).
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