t‐(ET) 2 Au(CN) 2  and t‐(ET) 2 AuBr 2 , Organic Radical Cation Salts with Twist Stucture | Zendy

Amberger Eberhard | Zendy; Fuchs Helmut | Zendy; Polborn Kurt | Zendy

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t‐(ET) 2 Au(CN) 2 and t‐(ET) 2 AuBr 2 , Organic Radical Cation Salts with Twist Stucture

Author(s) -

Amberger Eberhard,

Fuchs Helmut,

Polborn Kurt

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198607291

Subject(s) - twist , chemistry , crystallography , radical ion , ion , superconductivity , ion exchange , inorganic chemistry , physics , condensed matter physics , organic chemistry , geometry , mathematics

Not only the size of the anions but also their “Pearson softness” is decisive for determining which structures (ET) 2 X radical‐cation salts form. Exchange of the anion in superconducting, two‐dimensional β‐(ET) 2 AuI 2 for Au(CN) 2 ⊖or AuBr 2 ⊖leads to quasi one‐dimensional twist structures with ET double bonds and two‐dimensional η and ζ structures, none of which is a superconductor.

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