ζ‐(ET) 2 AuBr 2 , a New Type of Structure for the Organic Radical Cation Salts (ET) 2 AuX 2 | Zendy

Amberger Eberhard | Zendy; Polborn Kurt | Zendy; Fuchs Helmut | Zendy

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ζ‐(ET) 2 AuBr 2 , a New Type of Structure for the Organic Radical Cation Salts (ET) 2 AuX 2

Author(s) -

Amberger Eberhard,

Polborn Kurt,

Fuchs Helmut

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198607271

Subject(s) - radical ion , organic superconductor , superconductivity , crystal structure , chemistry , type (biology) , organic compound , crystallography , inorganic chemistry , ion , physics , organic chemistry , condensed matter physics , geology , paleontology

The search for organic metals and superconductors containing ET radical cations has led, by systematic variation of the anions, to ζ‐(ET) 2 AuBr 2 , a compound having a novel arrangement of the SċS network, which is decisive for the electrical properties. However, the compound is not a superconductor. In the crystal, the ET radical cations form stacks with SċS separations of <3.8 Å. The stacks are linked together to form two‐dimensional layers, in which four very short SċS contacts (<3.5 Å) are present.

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