[(Cp 2 Lu{μ‐PPh 2 } 2 Li(tmeda)] · 1/2 C 6 H 5 CH 3 , the First Organolanthanoid‐Phosphane Compound to be Characterized by X‐Ray Structure Analysis | Zendy

Schumann Herbert | Zendy; Palamidis Eftimios | Zendy; Schmid Günther | Zendy; Boese Roland | Zendy

Premium

[(Cp 2 Lu{μ‐PPh 2 } 2 Li(tmeda)] · 1/2 C 6 H 5 CH 3 , the First Organolanthanoid‐Phosphane Compound to be Characterized by X‐Ray Structure Analysis

Author(s) -

Schumann Herbert,

Palamidis Eftimios,

Schmid Günther,

Boese Roland

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198607181

Subject(s) - chemistry , ring (chemistry) , substitution (logic) , crystallography , stereochemistry , computer science , organic chemistry , programming language

A puckered four‐membered LuP 2 Li ring is the core of the title compound 1 , which was obtained by reaction of the corresponding di‐μ‐methyl complexes with HPPh 2 , via stepwise substitution of the methyl ligands. The X‐ray structure analysis of 1 has allowed elucidation of the bonding relationships in organolanthanoid‐phosphane compounds, which are of interest as mild agents for R 2 P transfer.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research