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A 1,2‐Diboratabenzene: Lithium Salt and Transition Metal Complexes
Author(s) -
Herberich Gerhard E.,
Hessner Bernd,
Hostalek Martin
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198606421
Subject(s) - lithium (medication) , salt (chemistry) , diborane , chemistry , derivative (finance) , ligand (biochemistry) , transition metal , cyclohexene , ion , inorganic chemistry , metal , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , boron , medicine , biochemistry , receptor , financial economics , economics , endocrinology
1,2‐Bis(dimethylamino)‐1,2‐diboratabenzene can be isolated as the crystalline Li(tmeda) Salt and structurally chracterized. The diborane(4) 1 affords the 1,2‐dibora‐4‐cyclohexene derivative 2 , which upon reaction with lithium tetramethylpiperidide (LiTMP) furnishes 3 . The anion of 3 has favorable ligand properties and could be inserted into Ru‐sandwich and Rh‐tripledecker complexes.