Nickelacyclobutabenzene Compounds by Oxidative Addition of Cyclopropabenzene to Nickel(0) Compounds | Zendy

Neidlein Richard | Zendy; Rufińska Anna | Zendy; Schwager Harald | Zendy; Wilke Günther | Zendy

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Nickelacyclobutabenzene Compounds by Oxidative Addition of Cyclopropabenzene to Nickel(0) Compounds

Author(s) -

Neidlein Richard,

Rufińska Anna,

Schwager Harald,

Wilke Günther

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198606401

Subject(s) - reactivity (psychology) , nickel , ring (chemistry) , chemistry , hydrolysis , oxidative addition , combinatorial chemistry , medicinal chemistry , oxidative phosphorylation , organic chemistry , catalysis , biochemistry , medicine , alternative medicine , pathology

The title reaction provides a novel and versatile entry to metallacyclobutabenzene compounds. The products 2 could be characterized both spectroscopically as well as by their reactivity. Thus, when L = n Bu 3 P the reaction with CO 2 leads via ring expansion to 3 , the hydrolysis product of which was identified as o ‐methylbenzoic acid.

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