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Synthesis and Dynamic Properties of Substituted Cyclohepta[ ef ]heptalene
Author(s) -
Hafner Klaus,
Knaup Günter L.,
Lindner Hans Jörg
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198606331
Subject(s) - chemistry , double bond , computational chemistry , distribution (mathematics) , stereochemistry , medicinal chemistry , organic chemistry , mathematics , mathematical analysis
Cycloheptale[ ef ]heptalene (pleiaheptalene) is the first peri‐annelated [4n]‐π‐electron system without aromatic partial structure . One of its derivatives that has now been synthesized is the compound 1 , RMe, which has exclusively the given double bond distribution. In solution an equilibrium is established with a π‐bond isomer.
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