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Methylene‐Bridged Dinuclear Gold( III ) Complexes with Terminal and Bridging Ylide Ligands
Author(s) -
Schmidbaur Hubert,
Hartmann Christoph
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198605751
Subject(s) - ylide , chemistry , isomerization , methylene , bridging (networking) , crystallography , stereochemistry , polymer chemistry , medicinal chemistry , organic chemistry , catalysis , computer network , computer science
Two exclusively C‐bonded gold atoms are present in the complex cation of 1 , which, except for the bonds to the CH 2 bridge, only contains onium‐stabilized Au‐C bonds. The salt 1 may be converted reversibly into the corresponding ylide without isomerization of the ligands.