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Bis(η 6 ‐arsabenzene)chromium(0)
Author(s) -
Elschenbroich Christoph,
Kroker Jörg,
Massa Werner,
Wünsch Martin,
Ashe Arthur J.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198605711
Subject(s) - chromium , electrochemistry , metal , ligand (biochemistry) , chemistry , atom (system on chip) , inorganic chemistry , electrode , organic chemistry , computer science , biochemistry , receptor , embedded system
The first sandwich complex of an unsubstitued neutral heteroarene , the title compound 1 , is formed by metal atom‐ligand cocondensation. The electrochemical oxidation of 1 is completely reversible, whereas the reduction is only partially reversible. Both potentials are anodically shifted compared with those of free arsabenzene.