Premium
Anionic Host Molecules with Bicyclic Carbon Skeletons—Synthesis and Guest Inclusion in Aqueous Solution
Author(s) -
Merz Thomas,
Wirtz Herbert,
Vögtle Fritz
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198605672
Subject(s) - benzene , molecule , aqueous solution , chemistry , bicyclic molecule , inclusion compound , host (biology) , benzene derivatives , inclusion (mineral) , stereochemistry , combinatorial chemistry , organic chemistry , chemical synthesis , in vitro , mineralogy , ecology , biochemistry , biology
The inclusion of neutral, organic guest molecules, e.g., benzene , in host compounds in aqueous solution has been achieved with the new cavity compound 1 , RCO 2 ⊖ Na ⊕ , and the analogue withCCH 3 instead of the two central benzene rings. The 1 H‐NMR signals of entrapped benzene molecules are strongly shifted to high field.