Spontaneous Intramolecular Ring Opening of the Cyclopropyl Group at a Metal‐Metal Double Bond | Zendy

Herrmann Wolfgang A. | Zendy; Herdtweck Eberhardt | Zendy; Weber Cornelia | Zendy

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Spontaneous Intramolecular Ring Opening of the Cyclopropyl Group at a Metal‐Metal Double Bond

Author(s) -

Herrmann Wolfgang A.,

Herdtweck Eberhardt,

Weber Cornelia

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198605631

Subject(s) - intramolecular force , ring (chemistry) , electrophile , chemistry , metal , group (periodic table) , double bond , stereochemistry , crystallography , medicinal chemistry , polymer chemistry , organic chemistry , catalysis

Thermally stable dimetallacyclopentanes 1 , RCH 3 and cyclo ‐C 3 H 5 , are obtained by the intramolecular addition of a cyclopropyl group to an electrophilic RhRh bond ( A → B , MRh); crucial for the stability of the complex 1 , which forms deep red, lustrous crystals, is the incorporation of the dimetallacyclopentane into a polycyclic framework.

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