[MoR(η 3 ‐C 3 H 5 ) 3 ], R = Alkyl: Alkylmolybdenum Complexes with Agostic CH ⇀ Mo Bond | Zendy

Benn Reinhard | Zendy; Holle Sigrid | Zendy; Jolly Peter W. | Zendy; Mynott Richard | Zendy; Romão Carlos C. | Zendy

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[MoR(η 3 ‐C 3 H 5 ) 3 ], R = Alkyl: Alkylmolybdenum Complexes with Agostic CH ⇀ Mo Bond

Author(s) -

Benn Reinhard,

Holle Sigrid,

Jolly Peter W.,

Mynott Richard,

Romão Carlos C.

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198605551

Subject(s) - agostic interaction , molybdenum , yield (engineering) , chemistry , alkyl , chloride , crystallography , stereochemistry , medicinal chemistry , inorganic chemistry , physics , organic chemistry , metal , thermodynamics

A dramatic high‐field shift of an 1 H‐NMR signal characterizes the agostic Mo↼HC interaction in the isopropylmolybdenum complex 2 . The bright yellow compound is accessible in 65% yield by reaction of the binuclear molybdenum complex 1 with isopropylmagnesium chloride at −78°C in ether.

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