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A Transition Metal Atom as Building Block of a Cyclic Phosphazene– Synthesis and Structure of [Cl 3 WN 3 (PPh 2 ) 2 ]
Author(s) -
Roesky Herbert W.,
Katti Kattesh V.,
Seseke Ulrich,
Witt Michael,
Egert Ernst,
Herbst Regine,
Sheldrick George M.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198604771
Subject(s) - phosphazene , ring (chemistry) , tungsten , chemistry , chlorine atom , salt (chemistry) , crystallography , chloroform , transition metal , solid state , atom (system on chip) , chlorine , block (permutation group theory) , polymer chemistry , stereochemistry , polymer , medicinal chemistry , organic chemistry , mathematics , geometry , computer science , embedded system , catalysis
A six‐membered planar WN 3 P 2 ring characterizes the structure of the title compound 3 ; probably a chlorine‐bridged polymer is present in the solid state. The yellow phosphazene 3 is formed upon reaction of tungsten hexachloride 1 with the salt 2 in chloroform.