A Transition Metal Atom as Building Block of a Cyclic Phosphazene– Synthesis and Structure of [Cl 3 WN 3 (PPh 2 ) 2 ] | Zendy

Roesky Herbert W. | Zendy; Katti Kattesh V. | Zendy; Seseke Ulrich | Zendy; Witt Michael | Zendy; Egert Ernst | Zendy; Herbst Regine | Zendy; Sheldrick George M. | Zendy

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A Transition Metal Atom as Building Block of a Cyclic Phosphazene– Synthesis and Structure of [Cl 3 WN 3 (PPh 2 ) 2 ]

Author(s) -

Roesky Herbert W.,

Katti Kattesh V.,

Seseke Ulrich,

Witt Michael,

Egert Ernst,

Herbst Regine,

Sheldrick George M.

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198604771

Subject(s) - phosphazene , ring (chemistry) , tungsten , chemistry , chlorine atom , salt (chemistry) , crystallography , chloroform , transition metal , solid state , atom (system on chip) , chlorine , block (permutation group theory) , polymer chemistry , stereochemistry , polymer , medicinal chemistry , organic chemistry , mathematics , geometry , computer science , embedded system , catalysis

A six‐membered planar WN 3 P 2 ring characterizes the structure of the title compound 3 ; probably a chlorine‐bridged polymer is present in the solid state. The yellow phosphazene 3 is formed upon reaction of tungsten hexachloride 1 with the salt 2 in chloroform.

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