P 6  t Bu 4 O and P 7  t Bu 5 O— the First Polycyclophosphane Oxides | Zendy

Baudler Marianne | Zendy; Michels Michael | Zendy; Pieroth Manfred | Zendy; Hahn Josef | Zendy

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P 6 t Bu 4 O and P 7 t Bu 5 O— the First Polycyclophosphane Oxides

Author(s) -

Baudler Marianne,

Michels Michael,

Pieroth Manfred,

Hahn Josef

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198604711

Subject(s) - ring (chemistry) , nmr spectra database , oxygen , chemistry , crystallography , stereochemistry , spectral line , medicinal chemistry , physics , organic chemistry , astronomy

In the oxidation of polycyclophosphanes , oxygen is bound exocyclically and is not inserted into the PP bonds. The P skeleton of the educts remains intact during the oxidation. l a and its isomer, with oxygen on P3 of the five‐mem‐bered ring, and 2a and 2b are obtained from P 6 , t Bu 4 , and P,tBu, respectively. Proof of the constitution of the compounds followed from the 31 P{ 1 H}‐NMR spectra, which could be taken from an NMR handbook.

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