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Synthesis and Structure of the First Arsaalkenyl Complex with FeAs Single Bond
Author(s) -
Weber Lothar,
Meine Georg,
Boese Roland
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198604691
Subject(s) - planar , crystallography , unit (ring theory) , bond , bond length , feature (linguistics) , single bond , materials science , skeleton (computer programming) , chemistry , computer science , mathematics , crystal structure , group (periodic table) , organic chemistry , computer graphics (images) , philosophy , business , programming language , linguistics , mathematics education , finance
The structural unit FeAsC is the characteristic feature of the title compounds 2 . They were prepared from 1 as outlined below. The Fe—As = C—O skeleton of 2a , R = t Bu, is planar; the As = C bond has a length of 182.1 pm.