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Unusual Behavior of the Stable Paramagnetic Dihydridoiridium( IV ) Complex [Ir(H) 2 (Cl) 2 ( i Pr 3 P) 2 ] in Solution
Author(s) -
Mura Pasquale,
Segre Annalaura
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198604601
Subject(s) - diamagnetism , paramagnetism , chemistry , crystallography , spectral line , nmr spectra database , physics , magnetic field , condensed matter physics , quantum mechanics , astronomy
A temperature‐dependent equilibrium between para‐1A and diamagnetic species 1B in solution was deduced from the surprisingly sharp 1 H‐ and 13 P‐NMR spectra of the title compound 1 . A kind of bonding could exist between 1B and H 2 . 1 is certainly present as 1A .