Premium
Diels‐Alder Adducts of Benzene with Arenes and Their [4+2] Cycloreversion
Author(s) -
Bertsch Achim,
Grimme Wolfram,
Reinhardt Gerd
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198603771
Subject(s) - adduct , benzene , chemistry , photochemistry , resonance (particle physics) , diels–alder reaction , benzene derivatives , medicinal chemistry , computational chemistry , organic chemistry , catalysis , chemical synthesis , biochemistry , in vitro , physics , particle physics
The retrocleavage of the adducts 1–5 proceeds according to a synchronous mechanism . The resonance energy gain in the products is 11 to 40 kcal/mol; in each case, 40% of this gain is reflected in a reduction of the energy of the transition state.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom