[Cp(CO) 2 Mo{NR * [Rh(norbornadiene)]‐CH(pyridyl)}], a Rhodium Complex with an Asymmetric Molybdenum Atom in the Chelate Skeleton | Zendy

Brunner Henri | Zendy; Wachter Joachim | Zendy; Schmidbauer Johann | Zendy; Sheldrick George M. | Zendy; Jones Peter G. | Zendy

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[Cp(CO) 2 Mo{NR * [Rh(norbornadiene)]‐CH(pyridyl)}], a Rhodium Complex with an Asymmetric Molybdenum Atom in the Chelate Skeleton

Author(s) -

Brunner Henri,

Wachter Joachim,

Schmidbauer Johann,

Sheldrick George M.,

Jones Peter G.

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198603711

Subject(s) - rhodium , norbornadiene , chemistry , molybdenum , chirality (physics) , ring (chemistry) , bent molecular geometry , crystallography , chelation , stereochemistry , inorganic chemistry , catalysis , organic chemistry , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark

Four centers of chirality—2 × C, 1 × N, 1 × Mo —are present in the title compound 1, R * = ( R )‐1‐CHMePh. Complex 1 is characterized, among other things, by a slightly bent CO group, which is in close contact to Rh. A complicated series of ring openings and epimerizations is suggested as a plausible route to 1 .

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