Bicyclic Host Cavities Derived from Triphenylamine—Guest Selectivity and Redox Properties | Zendy

Schrage Heinrich | Zendy; Franke Joachim | Zendy; Vögtle Fritz | Zendy; Steckhan Eberhard | Zendy

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Bicyclic Host Cavities Derived from Triphenylamine—Guest Selectivity and Redox Properties

Author(s) -

Schrage Heinrich,

Franke Joachim,

Vögtle Fritz,

Steckhan Eberhard

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198603361

Subject(s) - triphenylamine , bicyclic molecule , redox , selectivity , chemistry , substrate (aquarium) , photochemistry , host (biology) , combinatorial chemistry , stereochemistry , organic chemistry , biology , catalysis , ecology

Large, substrate‐selective cavities are present in the new, water‐soluble macrobicyclic compounds 1 , X, Y N, and 2 , X N, Y C‐CH 3 . Because the triphenylamine nitrogen can be oxidized electrochemically to the radical cation, these host compounds may be electrochemically modified (“switched on and off”). Compounds such as 1 and 2 are also of interest as models for redox enzymes.

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