Solvent Polarity and the Anomeric Effect | Zendy

Fuchs Benzion | Zendy; Ellencweig Aviyakar | Zendy; Tartakovsky Evgeny | Zendy; Aped Pinchas | Zendy

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Solvent Polarity and the Anomeric Effect

Author(s) -

Fuchs Benzion,

Ellencweig Aviyakar,

Tartakovsky Evgeny,

Aped Pinchas

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198602871

Subject(s) - anomer , polar , quadrupole , polarity (international relations) , dipole , chemistry , solvent , anomeric effect , solvent effects , solvent polarity , computational chemistry , chemical polarity , stereochemistry , organic chemistry , physics , atomic physics , quantum mechanics , biochemistry , cell

Polar solvents enhance the anomeric effect. This surprising turnabout follows from the NMR data and calculated dipole moments of dioxane derivatives such as 1 and 2 . Accordingly, polar solvents stabilize the diaxial conformation in 2 , RSiMe 3 , t Bu; in these compounds μ eq ≈ μ ax . Contributions by quadrupole moments etc. Were not taken into account.

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