Hydroxyacetylene: Generation and Characterization of the Neutral Molecule, Radical Cation and Dication in the Gas Phase | Zendy

van Baar Ben | Zendy; Weiske Thomas | Zendy; Terlouw Johan K. | Zendy; Schwarz Helmut | Zendy

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Hydroxyacetylene: Generation and Characterization of the Neutral Molecule, Radical Cation and Dication in the Gas Phase

Author(s) -

van Baar Ben,

Weiske Thomas,

Terlouw Johan K.,

Schwarz Helmut

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198602821

Subject(s) - dication , chemistry , radical ion , gas phase , molecule , mass spectrometry , cleavage (geology) , stripping (fiber) , characterization (materials science) , charge (physics) , fragmentation (computing) , ion , analytical chemistry (journal) , photochemistry , organic chemistry , materials science , nanotechnology , physics , chromatography , fracture (geology) , composite material , computer science , operating system , quantum mechanics

The simplest ynol, the title compound 2 , like the singly and doubly positively charged species 3 and 4 , respectively, could be generated in the mass spectrometer. Cleavage of CO from 1 furnished the radical cation 3 , which on neutralization with Xe affords the neutral ynol 2 . The radical cation 3 can be converted into the dication 4 by charge stripping.

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