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Hydroxyacetylene: Generation and Characterization of the Neutral Molecule, Radical Cation and Dication in the Gas Phase
Author(s) -
van Baar Ben,
Weiske Thomas,
Terlouw Johan K.,
Schwarz Helmut
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198602821
Subject(s) - dication , chemistry , radical ion , gas phase , molecule , mass spectrometry , cleavage (geology) , stripping (fiber) , characterization (materials science) , charge (physics) , fragmentation (computing) , ion , analytical chemistry (journal) , photochemistry , organic chemistry , materials science , nanotechnology , physics , chromatography , fracture (geology) , composite material , computer science , operating system , quantum mechanics
The simplest ynol, the title compound 2 , like the singly and doubly positively charged species 3 and 4 , respectively, could be generated in the mass spectrometer. Cleavage of CO from 1 furnished the radical cation 3 , which on neutralization with Xe affords the neutral ynol 2 . The radical cation 3 can be converted into the dication 4 by charge stripping.