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2‐Dewar Phosphinines—a New Class of Compounds Containing Two‐Coordinate Phosphorus
Author(s) -
Fink Jürgen,
Rösch Wolfgang,
Vogelbacher UweJosef,
Regitz Manfred
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198602801
Subject(s) - ring (chemistry) , chemistry , crystallography , double bond , oxygen , phosphorus , class (philosophy) , stereochemistry , polymer chemistry , organic chemistry , computer science , artificial intelligence
The first Dewar phosphabenzenes , which at the same time contain the first four‐membered ring with a PC double bond, namely the title compounds 1 , are surprisingly stable towards heat and oxygen. 1 , R 1 =Me, R 2 =1‐adamantyl, has been characterized by an X‐ray structure analysis.