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Reversible Interconversion of CC and CN Multiple Bond Systems on Clusters
Author(s) -
Bernhardt Wolfgang,
von Schnering Christine,
Vahrenkamp Heinrich
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198602791
Subject(s) - cluster (spacecraft) , chemistry , transformation (genetics) , crystallography , metal , stereochemistry , computational chemistry , organic chemistry , computer science , biochemistry , gene , programming language
Cluster moieties can be so conditioned by metal exchange that they support one and the same reaction in the region of the organic ligands both in the forward and reverse direction. A spontaneous alkylidyne‐vinylidene transformation has been observed for the first time within the sequences of the type shown below.