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Palladium( II ) and Platinum( II ) Complexes of 1,4,7,10,13,16‐Hexathiacyclooctadecane
Author(s) -
Blake Alexander J.,
Gould Robert O.,
Lavery Aidan J.,
Schröder Martin
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198602742
Subject(s) - palladium , platinum , chemistry , crown ether , ligand (biochemistry) , stereochemistry , crystallography , ether , medicinal chemistry , ion , catalysis , organic chemistry , receptor , biochemistry
A new form of coordination of the versatile ligand hexathia[18]crown‐6 is found in the title compounds: Pd or Pt is coordinated to four S atoms in a square planar fashion; only long range weak axial interactions are observed with the two remaining S atoms of the macrocycle. That is, the macrocycle does not behave like a crown ether.