A Simple Access to 2‐Epoxy Alcohols: Titanium( IV )‐Catalyzed Oxygen Transfer from Allylic Hydroperoxides | Zendy

Adam Waldemar | Zendy; Griesbeck Axel | Zendy; Staab Eugen | Zendy

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A Simple Access to 2‐Epoxy Alcohols: Titanium( IV )‐Catalyzed Oxygen Transfer from Allylic Hydroperoxides

Author(s) -

Adam Waldemar,

Griesbeck Axel,

Staab Eugen

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198602691

Subject(s) - allylic rearrangement , epoxy , chemistry , catalysis , alcohol , allylic alcohol , titanium , oxygen , combinatorial chemistry , allyl alcohol , organic chemistry , polymer chemistry

A host of new, synthetically valuable 2‐epoxy alcohols 3 should be accessible by the generally applicable title reaction. Oxygen transfer from 1 does not proceed intramolecularly; the first step is the formation of the allylic alcohol 2 , which is epoxidized in a rapid secondary step by 1 to the product 3 . At the same time, compound 2 is reformed.

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