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Benzophenone O ‐Oxide
Author(s) -
Sander Wolfram
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198602551
Subject(s) - benzophenone , oxide , chemiluminescence , matrix isolation , matrix (chemical analysis) , oxygen , chemistry , isolation (microbiology) , photochemistry , molecule , organic chemistry , chromatography , bioinformatics , biology
The oxidation of diphenylcarbene 1 to benzophenone O ‐oxide 2 with molecular oxygen has been elucidated by a matrix isolation technique. 2 is stable in the matrix at 10K and can be detected spectroscopically. The well‐known chemiluminescence is observed in the reaction of 2 with 1 .
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