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Heteronuclear ‘Star Clusters’: [Ni 2 Pt 2 W 4 (μ 3 ‐CPh) 4 (CO) 8 (η‐C 5 H 5 ) 4 ] and [Ni 2 Pt 2 W 4 (μ 2 ‐CR)(μ 3 ‐CR) 3 (CO) 8 (η‐C 5 H 5 ) 4 ] (R = Ph or p ‐C 6 H 4 Me)
Author(s) -
Elliott Gregory P.,
Howard Judith A. K.,
Mise Takaya,
Nunn Christine M.,
Stone F. Gordon A.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198601901
Subject(s) - carbyne , heteronuclear molecule , crystallography , ring (chemistry) , atom (system on chip) , metal , materials science , chemistry , physics , stereochemistry , nuclear magnetic resonance spectroscopy , carbene , biochemistry , organic chemistry , computer science , metallurgy , embedded system , catalysis
An eight‐membered ring of metal atoms forms the skeleton of the novel title compounds, the first of which is characterized by a special symmetry. The ring is held to gether in a starlike arrangement by four PhC ligands (only the carbyne C atom is shown).