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Thianthrene 5‐Oxide as Mechanistic Probe in Oxygen Transfer Reactions: Substrate Complexation in Oxidations with Transition Metal Peroxides
Author(s) -
Adam Waldemar,
Lohray B. Bhushan
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198601881
Subject(s) - thianthrene , chemistry , substrate (aquarium) , oxide , sulfur , sulfide , oxygen , transition metal , metal , photochemistry , inorganic chemistry , catalysis , organic chemistry , oceanography , geology
Whether complexation of the substrate is involved in oxidations with transition metal peroxides is still unclear. The findings illustrated below — SSO 2 :SOSO ≈ 1:1, only cis ‐ SOSO —can be interpreted by assuming complexation of the sulfide sulfur of SSO and subsequent transannular transfer of oxygen.