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[Co 4 (μ 3 ‐As) 3 )(μ 3 ,η 3 ‐As 3 )(PPh 3 ) 4 ], a Product of the Reaction of [CoCl 2 (PPh 3 ) 2 ] with PhAs(SiMe 3 ) 2
Author(s) -
Fenske Dieter,
Hachgenei Johannes
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198601751
Subject(s) - tetrahedron , crystallography , cluster (spacecraft) , ring (chemistry) , product (mathematics) , chemistry , physics , atomic physics , mathematics , geometry , computer science , organic chemistry , programming language
A ring containing three As atoms (white) is linked in a novel fashion to a tetrahedron of four Co atoms (black) in the Co 4 As 6 core of the title cluster compound. The other As atoms cap the remaining three faces of the tetrahedron. (The four PPh 3 groups bonded to the Co atoms are omitted).