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A Simple Route to the Intramolecular Quinhydrone of [2.2]Paracyclophanediene
Author(s) -
Stöbbe Michael,
Kirchmeyer Stephan,
Adiwidjaja Gunadi,
de Meijere Armin
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198601711
Subject(s) - intramolecular force , simple (philosophy) , charge (physics) , computational chemistry , singlet oxygen , molecule , singlet state , chemistry , chemical physics , stereochemistry , physics , atomic physics , oxygen , quantum mechanics , organic chemistry , philosophy , epistemology , excited state
Molecules exhibiting intramolecular charge transfer serve, among other things, as rigid models for the experimental determination of the dependence of this interaction (which is important in photosynthesis) on distance. The title compound 1 is particularly suitable for such studies. Compound 1 was obtained via a very short route by twofold addition of singlet oxygen to [2.2]paracyclophanediene.
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