Decamethylsilicocene—Synthesis and Structure | Zendy

Jutzi Peter | Zendy; Kanne Dieter | Zendy; Krüger Carl | Zendy

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Decamethylsilicocene—Synthesis and Structure

Author(s) -

Jutzi Peter,

Kanne Dieter,

Krüger Carl

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198601641

Subject(s) - conformational isomerism , silicon , divalent , atom (system on chip) , reduction (mathematics) , unit (ring theory) , crystallography , chemistry , materials science , stereochemistry , molecule , mathematics , computer science , geometry , organic chemistry , parallel computing , mathematics education

The first molecular compound of divalent silicon that is stable under normal conditions and the first π‐complex with silicon as the central atom is decamethylsilicocene 2 . It was prepared by reduction of 1 with naphthalenelithium, naphthalenesodium, or naphthalenepotassium. Two conformers in the ratio 1:2 are present in the unit cell.

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