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The Structure of Chlorosilyl‐ N , N ‐dimethylamine in the Gaseous and Solid Phases
Author(s) -
Anderson David G.,
Blake Alexander J.,
Cradock Stephen,
Ebsworth E. A. V.,
Rankin David W. H.,
Welch Alan J.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198601071
Subject(s) - dimer , dimethylamine , sn2 reaction , crystallography , monomer , chemistry , bond length , materials science , crystal structure , stereochemistry , polymer , organic chemistry
The dimer 1 can be regarded as a frozen‐in intermediate of an S N 2 reaction. It is present in crystals of the title compound. The gaseous compound is monomeric; bond lengths and angles deviate markedly from those of the crystalline dimer.