Polymeric (η 5 ,μ‐2,3‐Dihydro‐1,3‐diborolyl)nickel—the First Polydecker Sandwich Compound | Zendy

Kuhlmann Thomas | Zendy; Roth Siegmar | Zendy; Rozière Jacques | Zendy; Siebert Walter | Zendy

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Polymeric (η 5 ,μ‐2,3‐Dihydro‐1,3‐diborolyl)nickel—the First Polydecker Sandwich Compound

Author(s) -

Kuhlmann Thomas,

Roth Siegmar,

Rozière Jacques,

Siebert Walter

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198601051

Subject(s) - nickel , polymer , extended x ray absorption fine structure , condensation polymer , materials science , polymer chemistry , chemistry , crystallography , metallurgy , composite material , physics , optics , absorption spectroscopy

An old idea in sandwich chemistry has now been realized: The black, film‐like polymer 2 was obtained by thermal polycondensation of the dinickel complex 1 in vacuo. The thermally very stable but oxygen‐sensitive 2 is a semiconductor. EXAFS investigations suggest a distorted polydecker sandwich structure.

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