Synthesis and Structure of 1,3‐Diphenyltriazenidogold( I ), a Tetrameric Molecule with Short Gold‐Gold Distances | Zendy

Beck Johannes | Zendy; Strähle Joachim | Zendy

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Synthesis and Structure of 1,3‐Diphenyltriazenidogold( I ), a Tetrameric Molecule with Short Gold‐Gold Distances

Author(s) -

Beck Johannes,

Strähle Joachim

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198600951

Subject(s) - rhombus , liquid ammonia , crystallography , denticity , molecule , ion , chemistry , cluster (spacecraft) , stereochemistry , ammonia , materials science , nanotechnology , crystal structure , organic chemistry , mathematics , geometry , computer science , programming language

A gold‐nitrogen cluster Au 4 N 12 is present in the title compound (phenyl groups not shown). It contains a rhombus of four Au + ions which are bridged alternately above and below the Au 4 plane by four bidentate diphenyltriazenido ligands. The compound can be obtained from AuI and Na(PhN 3 Ph) in liquid ammonia.

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