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Synthesis and Structure of 1,3‐Diphenyltriazenidogold( I ), a Tetrameric Molecule with Short Gold‐Gold Distances
Author(s) -
Beck Johannes,
Strähle Joachim
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198600951
Subject(s) - rhombus , liquid ammonia , crystallography , denticity , molecule , ion , chemistry , cluster (spacecraft) , stereochemistry , ammonia , materials science , nanotechnology , crystal structure , organic chemistry , mathematics , geometry , computer science , programming language
A gold‐nitrogen cluster Au 4 N 12 is present in the title compound (phenyl groups not shown). It contains a rhombus of four Au + ions which are bridged alternately above and below the Au 4 plane by four bidentate diphenyltriazenido ligands. The compound can be obtained from AuI and Na(PhN 3 Ph) in liquid ammonia.