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Synthesis, Structure, and Addition Reactions of [Cp(CO) 2 W = PR 2 ], R = i Pr, t Bu
Author(s) -
Jörg Klaus,
Malisch Wolfgang,
Reich Wolfgang,
Meyer Angelika,
Schubert Ulrich
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198600921
Subject(s) - dehydrohalogenation , chemistry , medicinal chemistry , stereochemistry , organic chemistry , catalysis
The W = PR 2 complexes 2 obtainable from 1 and R 2 PH by dehydrohalogenation react with chlorophosphanes to give the complex salts 3 , whose cations contain the first side‐on coordinated diphosphane ligands (R = i Pr, t Bu; R′= i Pr, Me).