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Synthesis of Deoxyhexoses from Divinylglycols—The Synthesis of D ‐ and L ‐Chalcose
Author(s) -
Küfner Ulrike,
Schmidt Richard R.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198600891
Subject(s) - chemistry
Carbohydrates and related natural products with desired D‐ or L‐configuration, e.g. L‐chalcose 2 , are obtainable in enantiomerically pure form in a few steps from divinylglycols such as 1 . Decisive is the kinetic resolution by Sharpless oxidation.
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