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A Stable Diozonide of a Conjugated Diene by Ozonolysis of 2,3,4,5‐Tetramethyl‐2,4‐hexadiene on Polyethylene
Author(s) -
Griesbaum Karl,
Volpp Willi
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198600811
Subject(s) - ozonolysis , polyethylene , olefin fiber , conjugated system , conjugated diene , diene , chemistry , organic chemistry , polymer chemistry , polymer , natural rubber , monomer
Ozonolysis on powdered polyethylene has also proven useful in the case of the olefin 1 : thus, 2 , the first stable diozonide, could be isolated and characterized. 2 forms two isomers, of m.p. 51 and < − 60°C, which can be stored for a few hours at room temperature and for periods of months at −20°C.