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Bis( tert ‐butyl)diphosphene as Building Block of a Trichromium Cluster. A Novel Type of Coordination of Diphosphenes
Author(s) -
Borm Jutta,
Huttner Gottfried,
Zsolnai Laszlo
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198510691
Subject(s) - thermal decomposition , cluster (spacecraft) , bridge (graph theory) , block (permutation group theory) , ligand (biochemistry) , fragment (logic) , chemistry , decomposition , type (biology) , stereochemistry , crystallography , computer science , combinatorics , biology , organic chemistry , mathematics , computer network , biochemistry , receptor , algorithm , ecology , anatomy
A Z ‐diphosphene fragment as side‐on and end‐on coordinated ligand as well as a μ 3 ‐P‐‐ t Bu bridge are present in the triangulo Cr 3 cluster 1 , which is formed by thermal decomposition (100°C) of t BuP[Cr(CO) 5 ] 2 .