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Simply Substituted Boraethenes
Author(s) -
Maier Günther,
Henkelmann Jochem,
Reisenauer Hans Peter
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198510651
Subject(s) - benzophenone , adduct , chemistry , thermal stability , argon , matrix (chemical analysis) , medicinal chemistry , photochemistry , organic chemistry , chromatography
The limits of stability of boraethenes—not containing bulky substituents —appear to have been reached with 2 . Compounds 2 are formed by the thermal cycloreversion of Diels–Alder adducts and can be isolated in an argon matrix or trapped with, e.g., benzophenone (XOCH 3 , N(CH 3 ) 2 ).