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Multiple Bonds between “Naked” Lead and Transition Metals—The First Example
Author(s) -
Herrmann Wolfgang A.,
Kneuper HeinzJosef,
Herdtweck Eberhardt
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198510621
Subject(s) - tetrahydrofuran , substituent , chemistry , transition metal , atom (system on chip) , double bond , lead (geology) , crystallography , stereochemistry , polymer chemistry , organic chemistry , catalysis , computer science , solvent , embedded system , geomorphology , geology
A substituent‐free Pb atom that is bonded though double bonds to two organomanganese fragments is present in complex 2 , which is surprisingly easy to prepare from the mononuclear complex 1 and PbCl 2 in tetrahydrofuran (THF). The MnPbMn skeleton is nearly linear.