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Isolation of the Stable Silaketimine t Bu 2 SiNSi t Bu 3
Author(s) -
Wiberg Nils,
Schurz Klaus,
Fischer Gerd
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198510531
Subject(s) - salt (chemistry) , lithium (medication) , chemistry , medicinal chemistry , ether , organic chemistry , endocrinology , medicine
The SiN bond of the silaketimine 2 , which is obtained by “thermal salt elimination” from the lithium compound 1 , can undergo numerous addition reactions. For example, reaction with methyl vinyl ether affords the [2+2] cycloadduct 3 .
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