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1,4‐Photocycloaddition of α‐Morpholinoacrylonitrile to 1‐Acylnaphthalenes
Author(s) -
Döpp Dietrich,
Krüger Carl,
Memarian Hamid Reza,
Tsay YiHung
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198510481
Subject(s) - olefin fiber , chemistry , combinatorial chemistry , organic chemistry , catalysis
The captodative olefin 2 can undergo smooth addition to acylnaphthalene 1 (RH, Me, Ph) to give the 1,4‐photocycloadduct 3 . Such reactions of naphthylcarbonyl derivatives are extremely rare and synthetically useful.