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Novel Reactions of Acyl Halides with Bis(trimethylsilyl) Telluride: C,Te and C,C Bond Formation
Author(s) -
Severengiz Tevfik,
du Mont WolfWalther,
Lenoir Dieter,
Voss Heike
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198510411
Subject(s) - tellurium , telluride , halide , chemistry , trimethylsilyl , medicinal chemistry , chloride , derivative (finance) , organic chemistry , financial economics , economics
Tellurium compounds are increasingly used in organic synthesis . The first telluroacetic acid derivative, the ester 3 , was identified by its mass spectrum. 3 decomposes spontaneously to give ( Z )‐ and ( E )‐2,3‐bis(trimethylsiloxy)‐2‐butene and tellurium. The starting material 2 is obtainable from 1 and acetyl chloride.
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