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As 12 t Bu 8 —a Tricyclo[6.4.0.0 2,6 ]dodecaarsane
Author(s) -
Baudler Marianne,
WietfeldtHaltenhoff Stefan
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198509911
Subject(s) - chemistry , spectroscopy , nuclear magnetic resonance spectroscopy , mass spectrometry , crystallography , stereochemistry , physics , chromatography , quantum mechanics
The first organoarsane containing twelve As atoms , the title compound 1 , has been prepared from t BuAsCl 2 , AsCl 3 and Mg as a bright yellow, light‐sensitive solid. The skeletal structure of 1 was elucidated by 1 H‐NMR and mass spectroscopy. Upon warming in solution, 1 disproportionates into other tert ‐butylcycloarsanes.