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A Novel Route to Pentamethylcyclopentadienyllutetium Alkoxides and Thiolates
Author(s) -
Schumann Herbert,
Albrecht Ilse,
Hahn Ekkehard
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198509851
Subject(s) - lanthanide , sulfur , ring (chemistry) , metal , chemistry , ligand (biochemistry) , stereochemistry , crystallography , polymer chemistry , combinatorial chemistry , organic chemistry , receptor , ion , biochemistry
A folded Lu(μ‐S) 2 Li four‐membered ring is present in the complex 1 , in which a hard metal of the lanthanoid series is complexed by a ligand that is bound via the soft element sulfur to the metal. The synthesis of 1 was accomplished by reaction of the (μ‐CH 3 ) 2 ‐analogue with t BuSH.
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