[μ‐N 2 H 2 {Ru(PPh 3 )dttd} 2 ], the First Diazene Complex with Sulfur‐Coordinated Transition Metal Centers (dttd = 2,3,8,9‐Dibenzo‐1,4,7,10‐ tetrathiadecane(2 –)) | Zendy

Sellmann Dieter | Zendy; Böhlen Elmar | Zendy; Waeber Michael | Zendy; Huttner Gottfried | Zendy; Zsolnai Laslo | Zendy

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[μ‐N 2 H 2 {Ru(PPh 3 )dttd} 2 ], the First Diazene Complex with Sulfur‐Coordinated Transition Metal Centers (dttd = 2,3,8,9‐Dibenzo‐1,4,7,10‐ tetrathiadecane(2 –))

Author(s) -

Sellmann Dieter,

Böhlen Elmar,

Waeber Michael,

Huttner Gottfried,

Zsolnai Laslo

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198509811

Subject(s) - ruthenium , molybdenum , hydrazine (antidepressant) , transition metal , sulfur , chemistry , metal , nitrogenase , stereochemistry , crystallography , inorganic chemistry , medicinal chemistry , catalysis , organic chemistry , nitrogen , nitrogen fixation , chromatography

The complex 2, in which trans ‐N 2 H 2 bridges two ruthenium centers , could, as illustrated below, be obtained from the hydrazine complex 1. 2 forms blackish‐green crystals with 2 CH 2 Cl 2 . Complexed diazene, such as is present in 2 , is probably the key compound in the reduction of N 2 at the iron and/or molybdenum centers of nitrogenases.

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