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Extensions of the Tricyclooctanone Concept. A General Principle for the Synthesis of Linearly and Angularly Annelated Triquinanes
Author(s) -
Demuth Martin,
Hinsken Werner
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198509731
Subject(s) - key (lock) , type (biology) , unit (ring theory) , chemistry , natural (archaeology) , stereochemistry , mathematics , biology , ecology , mathematics education , paleontology
Oxadi‐π‐methane rearrangements are the key steps of a synthesis of the title compounds of type 1 and 2 . Triquinane is of special interest as a skeletal unit of natural products, e.g. hirsutene and 5‐oxosilphiperfol‐6‐ene.