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Nickel( 0 )‐Catalyzed Synthesis of Sorbanilide from 1,3‐Pentadiene and Phenyl Isocyanate
Author(s) -
Hoberg Heinz,
Hernandez Elisa
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198509611
Subject(s) - isocyanate , catalysis , chemistry , nickel , derivative (finance) , conjugated system , coupling reaction , polymer chemistry , organic chemistry , combinatorial chemistry , medicinal chemistry , polyurethane , polymer , business , finance
The preparation of the title compound 2 from 1,3‐pentadiene and phenyl isocyanate constitutes the first metal‐induced synthesis of a conjugated dienecarboxylic acid derivative. The reaction proceeds via CC coupling to give 1 , from which the anilide 2 is immediately formed.
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