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Synthesis and Structure of 1,4‐Dimethylanthracenemagnesium·3thf and μ‐Trichlorodimagnesium·6thf(1+) Anthracenide
Author(s) -
Bogdanović Borislav,
Janke Nikolaus,
Krüger Carl,
Mynott Richard,
Schlichte Klaus,
Westeppe Uwe
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198509601
Subject(s) - anthracene , tetrahydrofuran , chemistry , ion , medicinal chemistry , crystallography , photochemistry , organic chemistry , solvent
An isolated anthracene radical anion is present in the crystalline μ‐trichlorodimagnesium·6 thf(1+) anthracenide 2 . Compound 2 can be obtained from Mg, anthracene, and MgCl 2 , or from the Mg‐complex 1 , anthracene, and MgCl 2 , in each case in tetrahydrofuran (THF).